GREEN CHEMISTRY绿色化学
GREEN CHEMISTRY(英文缩写 GREEN CHEM),ISSN 1463-9262,eISSN 1463-9270,中文译名:绿色化学 是一本学术期刊。本页汇总该期刊的最新影响因子、分区信息以及最新收录于 PubMed 的文献,帮助您快速了解期刊全貌。
发文量统计区间：2025-11-01 至 2026-10-31，按本站收录文献的发表日期统计。
期刊介绍
历年影响因子趋势
| JCR 数据年份 | 影响因子 | JCR 分区 |
|---|---|---|
| 2021 | 11.034 | Q1 |
| 2022 | 9.800 | Q1 |
| 2023 | 9.300 | Q1 |
| 2024 | 9.200 | Q1 |
| 2025 | 10.600 | Q1 |
GREEN CHEMISTRY 最新收录文献
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1. Paving the way toward highly reversible aluminum metal anodes: the core role of ionic liquid electrolyte systems.
1. 为高可逆性铝金属负极铺平道路：离子液体电解质体系的核心作用PMID:日期:2026-09-25Rechargeable aluminum-ion batteries (AIBs) are promising candidates for next-generation energy storage, yet their practical deployment is hampered by the intrinsic limitations of conventional ionic liquid (IL) electrolytes, such as high viscosity, corrosivity, and moisture sensitivity. This review focuses on the core role of IL electrolyte design in enabling highly reversible aluminum metal anodes. First, the fundamental requirements and working mechanisms of ILs are systematically elucidated. Furthermore, recent optimization strategies are critically summarized and discussed in terms of four aspects: (1) cation-anion pair engineering to regulate active aluminum species, tailor physicochemical properties, and reduce reliance on costly imidazolium-based components, (2) functional additives to enhance ion transport and regulate solid electrolyte interphase (SEI) formation, (3) deep eutectic solvent formulations as potentially lower-cost and more sustainable alternatives, and (4) gel and quasi-solid-state architecture construction to improve safety and mechanical strength. Finally, the performance-sustainability trade-offs of current IL electrolyte systems are discussed, and design guidelines are provided for developing safer and more sustainable electrolytes with high ionic conductivity, wide electrochemical windows, and robust interfacial compatibility. These advancements are expected to facilitate the realization of highly reversible aluminum metal anodes and high-energy-density AIBs, thereby propelling the development of next-generation aluminum-based energy storage technologies.
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2. Green surfactants reveal mechanistic principles governing polymeric microbubble formation and function.
PMID:日期:2026-08-28Poly(butyl cyanoacrylate) microbubbles (PBCA MB) are clinically investigated ultrasound-responsive materials whose formation is governed by surfactant-mediated interfacial templating. Here, we used a chemically diverse panel of 14 commercially designated greener non-ionic surfactants to clarify how surfactant chemistry governs PBCA MB formation and performance. By combining physicochemical analysis, dissipative particle dynamics simulations, microscopy, drug-loading experiments, and acoustic characterization, we determined how the architecture of the hydrophobic moiety, PEG chain length, and hydrophilic-lipophilic balance shape MB yield, shell composition, morphology, and function. The hydrophobic tail structure primarily influenced MB yield, while increasing PEG chain length shifted the morphology toward asymmetric particles. Surfactant incorporation into PBCA MB shells depended on surfactant hydrophilic-lipophilic balance, and dissipative particle dynamics simulations indicated preferential surfactant enrichment at the polymer-water interface. Brij O20 and Ecosurf SA-9 increased drug loading by 6.2- and 4.8-fold relative to conventional Triton X-100-generated MB, while acoustic performance could be tuned toward either greater stability or stronger non-linear, disruption-prone behavior. Together, these findings clarify the role of surfactant chemistry in PBCA MB synthesis and promote surfactant design as a practical route to tailor MB morphology, shell composition, drug loading, and acoustic performance.
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3. {"_":"Optimal sizing of renewable generation and storage for grid-connected CO electrolysis: a Dutch case study on syngas production for e-SAF.","sub":["2"]}
3. {"_":"并网CO电解的可再生能源发电与储能的优化配置：以荷兰电子可持续航空燃料合成气生产为例","sub":["2"]}PMID:日期:2026-08-19Co-electrolysis of CO (COE) and water enables the production of syngas for sustainable aviation fuels (SAF) that are compliant with European RFNBO (renewable fuels of non-biological origin) regulations. However, a mismatch exists between the intermittent renewable electricity supply and the continuous operation of the downstream Fischer-Tropsch plants. To address this, we developed a two-stage linear optimization model to optimize the operation of a 540 MW electrolysis plant, alongside the sizing and operation of the connected renewable generation, battery storage, and syngas storage. Applying this model to a Dutch case study, we explored grid integration with an electrolyzer across future scenarios with global warming potentials (GWPs) ranging between 35 and 370 g CO-eq per kWh. For generation, the preferred renewable mix is onshore wind combined with PV. When grid mix electricity consumption is restricted, the electrolyzer has an optimal capacity factor of 78% but requires a battery of comparable capacity to the electrolyzer and multi-kilotonne syngas storage to ensure continuous output. Crucially, we found that producing RFNBO-compliant syngas for SAF is impossible with the 2025 Dutch grid mix. Even at a reduced grid intensity of 205 g CO-eq per kWh, RFNBO compliance limits grid consumption to just 1% of grid mix electricity per hour. This results in a levelized cost of 2350 EUR per tonne syngas. Unrestricted grid electricity consumption becomes feasible when emissions drop below 36 g CO-eq per kWh, reducing production costs by 43% (1344 EUR per tonne syngas). Consequently, we demonstrate that grid composition intensity is a bottleneck for the short-term economic viability and regulatory compliance of COE-based SAF in the Netherlands.
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4. Recent advances in xylochemicals of interest to the paints and coatings industry.
4. 近期对涂料和油漆行业具有重要意义的木基化学品研究进展PMID:日期:2026-08-17Xylochemicals, bio-based platform molecules isolated from wood-based waste streams, have been of particular interest to those in the paints and coatings industry seeking to increase bio-based content in their products. This tutorial review provides an introduction to the area, and covers recent advances across three key platforms: furfural and 5-hydroxymethylfurfural, vanillin, and cardanol derivatives, as well as an overview of other lignocellulosic platform molecules currently under investigation.
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5. Recyclable and bio-based waterborne acetal thermosets and composites.
PMID:日期:2026-08-15Fully recyclable waterborne acetal thermosets were synthesized the condensation of sorbitol and glutaraldehyde, utilizing oxalic acid as a green and decomposable catalyst. a simple one-pot polycondensation in water the catalyst-free densely crosslinked networks are formed, combining high mechanical performance (tensile strength >90 MPa), stiffness (Young's modulus 3.3 GPa), and excellent thermal and solvent stability. While the materials remain fully stable under neutral conditions, the acetal linkages enable complete depolymerization under acidic environments, producing a homogeneous solution that can be recondensed into new thermosets with properties indistinguishable from the original, thus achieving true closed-loop recycling. The resins also exhibit outstanding compatibility with glass and carbon fibers, enabling the fabrication of high-performance, recyclable composites from which pristine fibers can be recovered. Together, these results establish waterborne, bio-based acetal chemistry as a scalable and sustainable platform for high-performance thermosets and fiber composites, offering a practical and circular route toward next-generation materials design.
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6. The selective and sequential chemical recycling of commodity polymers with imino-indole zinc(ii) catalysts.
6. 使用亚氨基吲哚锌(ii)催化剂对大宗聚合物进行选择性和顺序化学回收PMID:日期:2026-08-13Chemical recycling of plastic waste will play a key role in both decoupling the plastics economy from fossil feedstocks and addressing growing global plastic pollution. Real-world plastic waste streams, however, are complex and heterogeneous, which presents a serious challenge to established chemical recycling methods. Here, we present a series of zinc complexes that show high activity for the chemical recycling of poly(lactic acid) (PLA), bisphenol A polycarbonate (BPA-PC), and poly(ethylene terephthalate) (PET). Crucially, the most active of these catalysts is capable of selectively deconstructing a mixed feed of these polymers in succession with selectivity governed by careful modulation of reaction temperature. This sequential approach allows for the products of each reaction to be isolated in high yields without the need for complex separations. Further, high activity is demonstrated for the direct depolymerization of PLA to lactide. This work demonstrates the feasibility of sequential chemical recycling of mixed plastic waste as a tool for a more circular plastics economy.
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7. {"_":"Deprotection of benzyl ethers solvent anion-mediated EDA complex.","i":["via"]}
PMID:日期:2026-07-13Benzyl ethers are among the most robust and indispensable protecting groups in the synthesis of complex natural products and pharmaceuticals, providing effective neutralization of the reactive hydroxy group in phenols and alcohols. However, their cleavage necessitates the use of expensive catalysts, hazardous conditions, or excessive organic additives. Herein, we report a catalyst-free, photoinduced debenzylation protocol of phenolic and aliphatic ethers. By leveraging generated solvent-anions as the reductant, the protocol achieves chemoselective debenzylation in the presence of alkenes, amides, carbamates, alcohols, and boronic esters in high yields under mild conditions. This strategy circumvents the need for costly hydrogenation catalysts or toxic reagents, providing a sustainable and economically viable alternative for debenzylation.
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8. Fully bio-based wood adhesives from lignin and zein protein.
8. 完全基于生物基的木质素和玉米醇溶蛋白木材胶黏剂PMID:日期:2026-06-24Manufacturing of wood-based panels predominantly relies on formaldehyde-containing adhesives, whose volatile organic compound emissions raise serious concerns about indoor air quality and human health. Although bio-based adhesives derived from proteins, polysaccharides, or lignin have been explored, achieving strong bonding performance while maintaining green, scalable, and practical processability remains challenging. In this study, we present a waterborne wood adhesive in which zein protein is dispersed within a viscous micellar lignin gel. Drawing inspiration from the interactions between proteins and polyphenols, we designed this system to be fully bio-based and free of cross-linkers. When birch veneers were hot-pressed with this adhesive, the resulting three- to five-layer plywood materials showed competitive performance compared with existing bio-based adhesive formulations. Meanwhile, this approach also delivers favorable green metrics, including an Eco-scale score of 94, supported by the absence of organic solvents, a minimal number of steps, and the waterborne nature of the formulation. Notably, the adhesive can be debonded in a 70% ethanol-water solution, allowing its recovery and reuse. The combined results indicate the potential of the lignin-protein system as a sustainable alternative to conventional petroleum-based commercial adhesives for indoor use.
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9. Valorization of birch tops and branches containing mechanically inseparable wood and bark.
PMID:日期:2026-06-01If valorization of tops and branches would be realized, there is potential to increase the overall yield from forestry by 50%, which would impact land use change and climate change considerably. Currently, these residues are either incinerated or left to decay in the forests. The main challenge of valorization of tops and branches is their composition: comprising both wood and bark that are mechanically inseparable. Herein, we propose a chemical approach to valorize all components of both wood and bark of tops and branches without prior mechanical separation. By applying a sequential fractionation sequence involving two different catalytic steps, all different parts of the tops and branches have been valorized into well-defined streams and an intact cellulose-rich pulp. It was found that the sequence of processes was important for the overall outcome. We hope that this first report of the valorization of tops and branches will inspire further studies to unlock the full potential of this challenging yet abundant feedstock.
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10. Thermally activated delayed fluorescence (TADF) compounds in energy transfer processes. A general alternative to metal-based complexes.
10. 能量转移过程中的热活化延迟荧光（TADF）化合物。金属配合物的一种通用替代方案PMID:日期:2026-05-22Recently, TADF (thermally activated delayed fluorescence) compounds have expanded their role beyond materials chemistry, enriching the field of photocatalysis and offering a cost-effective and environmentally friendly alternative to classical metal-based complexes. However, while their role in photoredox catalysis is well-established, research on their use in EnT reactions is sparse. In this tutorial review, we discuss and summarise the observed reactivity trends for some leading families of TADF compounds. Further, we examine their structure-property relationships and explore the development of synthetic methods for greener, more sustainable protocols in which TADF molecules serve as crucial catalytic systems.