Applied Catalysis B-Environment and Energy应用催化B：环境与能源
Applied Catalysis B-Environment and Energy(英文缩写 APPL CATAL B-ENVIRON),ISSN 0926-3373,eISSN 1873-3883,中文译名:应用催化B：环境与能源 是一本学术期刊。本页汇总该期刊的最新影响因子、分区信息以及最新收录于 PubMed 的文献,帮助您快速了解期刊全貌。
发文量统计区间：2025-11-01 至 2026-10-31，按本站收录文献的发表日期统计。
期刊介绍
历年影响因子趋势
| JCR 数据年份 | 影响因子 | JCR 分区 |
|---|---|---|
| 2021 | 24.319 | Q1 |
| 2022 | 22.100 | Q1 |
| 2023 | 20.200 | Q1 |
| 2024 | 21.100 | Q1 |
| 2025 | 19.700 | Q1 |
Applied Catalysis B-Environment and Energy 最新收录文献
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1. Surface-catalyzed hydrolysis by pyrogenic carbonaceous matter and model polymers: An experimental and computational study on functional group and pore characteristics.
PMID:日期:2022-09-06We employed a polymer network to understand what properties of pyrogenic carbonaceous matter (PCM; ., activated carbon) confer its reactivity, which we hereinafter referred to as PCM-like polymers (PLP). This approach allows us to delineate the role of functional groups and micropore characteristics using 2,4,6-trinitrotoluene (TNT) as a model contaminant. Six PLP were synthesized via cross-coupling chemistry with specific functionality (-OH, -NH, -N(CH), or ) and pore characteristics (mesopore, micropore). Results suggest that PCM functionality catalyzed the reaction by: (1) serving as a weak base (-OH, -NH) to attack TNT, or (2) accumulating OH near PCM surfaces (). Additionally, TNT hydrolysis rates, pH and co-ion effects, and products were monitored. Microporous PLP accelerated TNT decay compared to its mesoporous counterpart, as further supported by molecular dynamics modeling results. We also demonstrated that quaternary ammonium-modified activated carbon enhanced TNT hydrolysis. These findings have broad implications for pollutant abatement and catalyst design.
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2. The role of trace N-Oxyl compounds as redox mediator in enhancing antiviral ribavirin elimination in UV/Chlorine process.
2. 微量N-氧基化合物作为氧化还原介体在增强UV/氯工艺中抗病毒药物利巴韦林去除的作用PMID:日期:2022-07-05Ribavirin (RBV) is an antiviral drug used for treating COVID-19 infection. Its release into natural waters would threaten the health of aquatic ecosystem. This study reports an effective approach to degrade RBV by the trace N-oxyl compounds (2,2,6,6-tetramethylpiperidine-N-oxyl (TEMPO) and N-Hydroxyphthalimide (NHPI)) enhanced UV activated free chlorine (UV/Chlorine) process. The results indicated that TEMPO and NHPI at low concentrations (0.1 μM and 1 μM, respectively) could strongly enhance RBV degradation in both deionized water with different pHs and practical surface water. The enhancement was verified to be attributed to the transformation of TEMPO and NHPI into their reactive forms (i.e., TEMPO and PINO), which generations deeply relied on radicals. The two N-oxyl compounds inhibit ClO• yield by hindering the reaction of free chlorine vs. HO• and Cl•. The analyses on acute toxicities of RBV degradation products indicate that UV/Chlorine/N-oxyl compounds process can detoxify RBV more efficiently than UV/Chlorine process.
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3. Novel franklinite-like synthetic zinc-ferrite redox nanomaterial: synthesis, and evaluation for degradation of diclofenac in water.
3. 新型类富兰克林合成铁酸锌氧化还原纳米材料：双氯芬酸在水中的合成和降解评价PMID:日期:2020-10-15The current study investigates a novel redox technology based on synthetic franklinite-like zinc-ferrite nanomaterial with magnetic properties and redox nature for potential use in water treatment. Physicochemical characterization revealed the nanoscale size and ABO spinel configuration of the zinc-ferrite nanomaterial. The redox activity of nanoparticles was tested for degradation of diclofenac (DCF) pharmaceutical in water, without any added external oxidants and under dark experimental conditions. Results revealed ~90% degradation in DCF (10 μM) within 2 min of reaction using 0.17 g/L ZnFeO. Degradation of DCF was due to chemical reduction by surface electrons on zinc-ferrite and oxidation by oxygen-based radicals. Three byproducts from reduction route and eight from oxidation pathways were identified in the reaction system. Reaction pathways were suggested based on the identified byproducts. Results demonstrated the magnetic zinc-ferrite is a standalone technology that has a great promise for rapid degradation of organic contaminants, such as DCF in water.
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4. {"_":"An approach to the photocatalytic mechanism in the TiO-nanomaterials microorganism interface for the control of infectious processes.","sub":["2"]}
4. {“_”：“一种控制感染过程的TiO纳米材料-微生物界面光催化机制的方法。”，“sub”：[“2”]}PMID:日期:2020-03-09The approach of this timely review considers the current literature that is focused on the interface nanostructure/cell-wall microorganism to understand the annihilation mechanism. Morphological studies use optical and electronic microscopes to determine the physical damage on the cell-wall and the possible cell lysis that confirms the viability and microorganism death. The key parameters of the tailoring the surface of the photoactive nanostructures such as the metal functionalization with bacteriostatic properties, hydrophilicity, textural porosity, morphology and the formation of heterojunction systems, can achieve the effective eradication of the microorganisms under natural conditions, ranging from practical to applications in environment, agriculture, and so on. However, to our knowledge, a comprehensive review of the microorganism/nanomaterial interface approach has rarely been conducted. The final remarks point the ideal photocatalytic way for the effective prevention/eradication of microorganisms, considering the resistance that the microorganism could develop without the appropriate regulatory aspects for human and ecosystem safety.
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5. Sonophotocatalytic degradation mechanisms of Rhodamine B dye via radicals generation by micro- and nano-particles of ZnO.
PMID:日期:2019-03-20In this work, it is proposed an environmental friendly sonophotocatalytic approach to efficiently treat polluted waters from industrial dyes exploiting ZnO micro- and nano-materials. For the first time, we deeply investigated the generation of reactive oxygen species (ROS) under ultrasound stimulation of different ZnO structures by Electron Paramagnetic Resonance Spectroscopy (EPR). Indeed, five zinc oxide (ZnO) micro- and nano-structures, Desert Roses (DRs), Multipods (MPs), Microwires (MWs), Nanoparticles (NPs) and Nanowires (NWs), were studied for the Rhodamine B (RhB) sonodegradation under ultrasonic irradiation. The DRs microparticles demonstrated the best sonocatalytic performance (100% degradation of RhB in 180 min) and the highest OH radicals generation under ultrasonic irradiation. Strikingly, the coupling of ultrasound and sun-light irradiation in a sonophotodegradation approach led to 100% degradation efficiency, color reduction, of RhB in just 10 min, revealing a great positive synergy between the photocatalytic and sonocatalytic mechanisms. The RhB sonophotocatalytic degradation was also evaluated at different initial dye concentrations and with the presence of anions in solution. It was demonstrated a good stability over repeated cycles of dye treatment, which probe the applicability of this technique with industrial effluents. In conclusion, sonophotocatalytic degradation synergizing sunlight and ultrasound in the presence of DRs microparticles shows a great potential and a starting point to investigate further the efficient treatment of organic dyes in wastewater.
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6. Size-Dependent Photocatalytic Activity of Carbon Dots with Surface-State Determined Photoluminescence.
6. 表面状态决定光致发光的碳点的尺寸依赖性光催化活性PMID:日期:2019-02-11Carbon dots (CDs) were synthesized by a microwave-mediated method and separated by size exclusion chromatography into three different size fractions. There was no correlation of the size with photoluminescence (PL) emission wavelength, which shows that the PL mechanism is not quantum-size dependent. UV/vis absorption and diffuse reflectance spectroscopies showed that the light absorption properties as well as the band gap of the CDs changed with the size of the particle. The combination of FTIR and XPS measurements revealed the composition on the surface of each fraction. The three CDs fractions were separately used in the photocatalytic degradation of organic dyes under simulated sunlight irradiation. The catalytic activity of the as-prepared CDs was found to increase as the size of the particles decreased. Complete degradation of both rhodamine B (RhB) and methylene blue (MB) was achieved in 150 min by the 2-nm CDs. The scavenger studies showed that the holes and superoxide radicals are the main species involved in the photocatalytic degradation of the dye by the 2-nm CDs. These CDs displayed high stability in the degradation of organic dyes for multiple cycles. The 2-nm CDs displayed promising photocatalytic degradation of p-nitrophenol (PNP) . These results demonstrate for the first time the application of bare carbon dots in the degradation of environmental contaminants.
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7. In situ grown Ni phosphide nanowire array on Ni foam as a high-performance catalyst for hydrazine electrooxidation.
PMID:日期:2019-02Synthesis of high-performance and cost-effective electrocatalysts towards hydrazine electrooxidation is vital to develop the direct hydrazine fuel cell (DHFC) as a viable energy conversion technology. Herein, we report a combined experimental and theoretical study of nickel phosphides (NiP) as promising catalysts for hydrazine electrooxidation. NiP nanowire array supported on a Ni foam (NF) was synthesized by a one-step phosphorization method using hypophosphite as a P-source. NiP and NiP phases are observed as the products of the direct phosphorization of commercial NF under the applied conditions with NiP nanoparticles exclusively distributing on the surface of NiP. The NiP/NF catalyst exhibits a synergetic capabilities of exceptionally high activity, excellent durability and nearly 100% selectivity towards the complete electrooxidation of hydrazine in alkaline condition, which is among the best performance reported on hydrazine electrooxidation catalysts. First-principles calculations have been conducted to gain insight into the catalytic mechanism of Ni phosphides towards hydrazine electrooxidation.
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8. Noble metal-modified faceted anatase titania photocatalysts: Octahedron versus decahedron.
PMID:日期:2018-12-05Octahedral anatase particles (OAP, with eight equivalent {101} facets) and decahedral anatase particles (DAP, with two additional {001} facets) were modified with nanoparticles of noble metals (Au, Ag, Cu). The titania morphology, expressed by the presence of different arrangements of exposed crystal facets, played a key role in the photocatalytic properties of metal-modified faceted titania. In the UV/vis systems, two-faceted configuration of DAP was more favorable for the reaction efficiency than single-faceted OAP because of an efficient charge separation described by the transfer of electrons to {101} facets and holes to {001} facets. Time-resolved microwave conductivity (TRMC) and reversed double-beam photoacoustic spectroscopy (RDB-PAS) confirmed that distribution of electron traps (ET) and mobility of electrons were key-factors of photocatalytic activity. In contrast, metal-modified OAP samples had higher photocatalytic activity than metal-modified DAP and metal-modified commercial titania samples under visible light irradiation. This indicates that the presence of single type of facets ({101}) is favorable for efficient electron transfer via shallow ET, whereas intrinsic properties of DAP result in fast charge carriers' recombination when gold is deposited on {101} facets (migration of "hot" electrons: Au→{101}→Au).
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9. Dehydration of fructose over thiol- and sulfonic- modified alumina in a continuous reactor for 5-HMF production: Study of catalyst stability by NMR.
9. 硫醇和磺酸改性氧化铝在连续反应器中催化果糖脱水制备5-HMF：通过NMR研究催化剂稳定性PMID:日期:2018-11-19In the present study, the synthesis of an organic group-modified alumina by the sol-gel method is proposed. This material has shown to have an enhanced catalytic performance with grafted organic groups and showed an improved stability. The prepared material has shown to have several groups and an enhanced surface acidity. The alumina acidity was improved by incorporating thiol groups by grafting method, which promotes the tautomerization of fructose to its furanose form. Furthermore, the grafting of sulfonic groups catalyzes its dehydration. The modified alumina was thermally treated up to 200 °C to improve the functional groups stability. After, this modified material was packed into a continuous reactor system, designed and built by this group, to obtain 5-hydroxymethylfurfural (5-HMF) from fructose dissolved in a single-phase solution of tetrahydrofuran (THF) and HO (4:1 w/w). The catalytic activity of this material was evaluated by the reaction of fructose dehydration at different reaction temperatures (60, 70, 80 and 90 °C). Fructose conversion and selectivity toward 5-HMF were determined by high performance liquid chromatography (HPLC), obtaining 95% and 73% respectively for the highest temperature. The catalyst showed an efficient stability after 24 hours in continuous flow at 70 °C. The loss of sulfur content was 15%, but the fructose conversion yield and the selectivity to 5-HMF after 24 hours of continuous reaction did not undergo significant changes (less than 5%). The nuclear magnetic resonance (NMR) tests confirmed the presence of the thiol and sulfonic groups before and after 24 hours of reaction, as well as the conservation of the same structure, demonstrating the efficient catalytic performance of the material. The catalysts were characterized by nitrogen adsorption/desorption, X-ray diffraction and infrared (IR) spectroscopy. Also, before and after use by utilizing elemental analysis and cross-polarization magic-angle spinning (CPMAS) and dynamic-nuclear polarization (DNP)-enhanced and CPMAS as well as directly excited magic-angle spinning (MAS) NMR methods in solid-state.
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10. Heterogeneous activation of persulfate by reduced graphene oxide-elemental silver/magnetite nanohybrids for the oxidative degradation of pharmaceuticals and endocrine disrupting compounds in water.
10. 还原氧化石墨烯-元素银/磁铁矿纳米杂化物对过硫酸盐的非均相活化，用于水中药物和内分泌干扰化合物的氧化降解PMID:日期:2018-06-05Reduced graphene oxide hybridized with zero-valent silver and magnetite nanoparticles (NPs) (rGO-Ag/FeO nanohybrids) prepared via nucleation and crystallization was used to activate peroxydisulfate (PDS) for degradation of pharmaceuticals and endocrine disrupting compounds (phenol, acetaminophen, ibuprofen, naproxen, bisphenol A, 17β-estradiol, and 17α-ethinyl estradiol). The deposition of Ag and FeO in rGO nanosheet enhanced the catalytic removal of phenol in the heterogeneous activation of PDS. The adsorption capacities of rGO-Ag/FeO for 10 μM phenol were 1.76, 1.33, and 2.04 μmol g-adsorbent at pH 4, 7, and 10, respectively, which are much higher than those of single NPs studied (Ag, nanoscale zero-valent iron, and rGO). The rGO-Ag/FeO effectively activated PDS to produce strong oxidizing SO·and facilitate an electron transfer on the surface of the nanohybrid. The initial pseudo-first-order rate ( ) constant for phenol degradation in PDS/rGO-Ag/FeO system was 0.46 h at pH 7, which is approximately eight times higher than that in the presence of single NPs ( = 0.04-0.06 h) due to the synergistic effects between adsorption and catalytic oxidation. Among various organic contaminants tested, the simultaneous use of rGO-Ag/FeO (0.1 g/L) and PDS (1 mM) achieved more than 99% degradation of acetaminophen and 17β-estradiol at pH 7. The radical scavenging studies with methanol and natural organic matter indicated that phenol was more likely to be degraded via free SO· and ·OH formation or a non-radical oxidative pathway. Our findings indicate that the rGO-Ag/Fe O nanohybrids can be used as an efficient magnetically-separable nanocatalyst for removal of organic compounds in water and wastewater treatment.