增强柔性钙钛矿太阳能电池的协同紫外转换和交联策略
Synergistic Ultraviolet Conversion and Cross-Linking Strategy for Enhancing Flexible Perovskite Solar Cells.
Synergistic Ultraviolet Conversion and Cross-Linking Strategy for Enhancing Flexible Perovskite Solar Cells.
柔性钙钛矿太阳能电池(fPSCs)在紫外(UV)照射下的运行稳定性仍是其户外应用面临的关键挑战。为此,我们开发了一种创新型交联单体TFMU-TA,其设计具有紫外下转换功能以解决该问题。聚(TFMU-TA)可保护钙钛矿薄膜免受紫外诱导降解,同时提升其整体质量与稳定性。因此,fPSCs实现了23.16%的功率转换效率。柔性器件在弯曲、紫外照射和湿热老化条件下表现出稳健的稳定性,同时在户外测试中保持可靠的输出功率。本工作为多功能交联材料提供了一种新颖的设计策略,从而促进fPSCs的持久户外部署。
The operational stability of flexible perovskite solar cells (fPSCs) under ultraviolet (UV) irradiation remains a critical challenge for their outdoor application. Herein, we develop an innovative cross-linking monomer, TFMU-TA, designed with a UV down-conversion function to address this issue. Poly(TFMU-TA) protects the perovskite film from UV-induced degradation while simultaneously enhancing its overall quality and stability. Consequently, the fPSCs achieve a power conversion efficiency of 23.16%. The flexible devices exhibited robust stability against bending, UV irradiation, and damp-heat aging, while also maintaining reliable output power in outdoor tests. This work provides a novel design strategy for multifunctional cross-linking materials, thereby facilitating the durable outdoor deployment of fPSCs.
Silong Tu, Jie Ning, Hanwen Dong, Xin Li. Synergistic Ultraviolet Conversion and Cross-Linking Strategy for Enhancing Flexible Perovskite Solar Cells.. ACS applied materials & interfaces. 2026; doi:10.1021/acsami.6c01787.
Silong Tu, Jie Ning, Hanwen Dong, Xin Li (2026). Synergistic Ultraviolet Conversion and Cross-Linking Strategy for Enhancing Flexible Perovskite Solar Cells.. ACS applied materials & interfaces. https://doi.org/10.1021/acsami.6c01787
Silong Tu, Jie Ning, Hanwen Dong, Xin Li. Synergistic Ultraviolet Conversion and Cross-Linking Strategy for Enhancing Flexible Perovskite Solar Cells.[J]. ACS applied materials & interfaces, 2026 doi:10.1021/acsami.6c01787.
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